Synthesis of mesoporous sorbents on the basis of Al2O3 and their textural characteristics
Keywords:
sol-gel, mesoporous sorbent, diffracrometry, specific surface, pores volume, X-ray microanalysis
Abstract
The samples of mesoporous sorbent based on Al2O3 were synthesized using sol-gel technology. The phase composition of the samples was studied by X-ray diffractometry (XRD), the surface morphology by scanning electron microscopy methods. Also, the textural characteristics of the sorbents were studied by adsorption of benzene vapors using McBen-Bakra sensitive quartz spiral device.
References
Yaqoob A. A. et al. Role of nanomaterials in the treatment of wastewater: a review //Water. – 2020. – Т. 12. – №. 2. – С. 495.
Nturanabo F., Masu L., Kirabira J. B. Novel applications of aluminium metal matrix composites //Aluminium Alloys and Composites. – 2019.
Khodakarami M., Bagheri M. Recent advances in synthesis and application of polymer nanocomposites for water and wastewater treatment //Journal of Cleaner Production. – 2021. – Т. 296. – С. 126404.
He Y. He, J., Wang L., Yu Z., Zhang H., Liu Y., Lei,B.Synthesis of double carbon dots co-doped mesoporous Al2O3 for ratiometric fluorescent determination of oxygen //Sensors and Actuators B: Chemical. – 2017. – Т. 251. – С. 918-926.
Wu Z., Q., Feng D., Webley P. A., Zhao D. Ordered mesoporous crystalline γ-Al2O3 with variable architecture and porosity from a single hard template //Journal of the American Chemical Society. – 2010. – Т. 132. – №. 34. – С. 12042-12050.
Fayomi O. S. I., Babaremu K. O., Akande I. G. Impact of Al-Composites in the Manufacturing Industry: A Neccessity //International Journal of Civil Engineering and Technology. – 2019. – Т. 10. – №. 3.
Szczęśniak B. Babaremu K. O., Akande I. G. Mechanochemical synthesis of highly porous materials //Materials Horizons. – 2020. – Т. 7. – №. 6. – С. 1457-1473.
Xifre-Perez Mesoporous alumina as a biomaterial for biomedical applications //Open Material Sciences. – 2015. – Т. 2. – №. 1. – С. 13-32.
Naik B., Ghosh N. N. A review on chemical methodologies for preparation of mesoporous silica and alumina based materials //Recent patents on nanotechnology. – 2009. – Т. 3. – №. 3. – С. 213-224.
Griffin, Sharoon, "Natural nanoparticles: a particular matter inspired by nature." Antioxidants 7.1 (2017): 3.
Wei, Jing, "Ordered mesoporous alumina with ultra-large pores as an efficient absorbent for selective bioenrichment." Chemistry of Materials 29.5 (2017): 2211-2217.
Wu, Y. S., Ma, J., Li, M. C., & Hu, F. (2013). Synthesis of γ-Al2O3 with high surface area and large pore volume by reverse precipitation-azeotropic distillation method. Chemical Research in Chinese Universities, 29(2), 206-209.
Wu, Yu-sheng, Jiao Ma, Ming-chun Li, and Fang Hu. "Synthesis of γ-Al2O3 with high surface area and large pore volume by reverse precipitation-azeotropic distillation method." Chemical Research in Chinese Universities 29, no. 2 (2013): 206-209.
Said, S., S. Mikhail, and M. Riad. "Recent processes for the production of alumina nano-particles." Materials Science for Energy Technologies 3 (2020): 344-363.
Sayed, E., Haj-Ahmad, R., Ruparelia, K., Arshad, M. S., Chang, M. W., & Ahmad, Z. (2017). Porous inorganic drug delivery systems—a review. Aaps Pharmscitech, 18(5), 1507-1525.
Toberer, E.S. and Seshadri, R., 2006. Template-free routes to porous inorganic materials. Chemical communications, (30), pp.3159-3165.
Ghanizadeh, S., Bao, X., Vaidhyanathan, B., & Binner, J. (2014). Synthesis of nano α-alumina powders using hydrothermal and precipitation routes: a comparative study. Ceramics International, 40(1), 1311-1319.
Yang, Yanping, Kunming Pan, Shizhong Wei, Wuhui Li, Liujie Xu, Jiwen Li, Fangnao Xiao et al. "Hydrothermal synthesis and adsorption property of porous spherical Al2O3 nanoparticles." Materials Research Express 6, no. 7 (2019): 075023.
Gaweł, Bartłomiej, Kamila Gaweł, and Gisle Øye. "Sol-gel synthesis of non-silica monolithic materials." Materials 3.4 (2010): 2815-2833.
Moein, Mohammad Mahdi, Abbi Abdel-Rehim, and Mohamed Abdel-Rehim. "Recent applications of molecularly imprinted sol-gel methodology in sample preparation." Molecules 24, no. 16 (2019): 2889.
Feinle, Andrea, Michael S. Elsaesser, and Nicola Huesing. "Sol–gel synthesis of monolithic materials with hierarchical porosity." Chemical Society Reviews 45, no. 12 (2016): 3377-3399.
Colleoni, Claudio. "Sol-gel synthesis and hybrid thin film deposition for innovative textile finishing. Study, characterization and environmental impact evaluation." (2012).
Uzokov J. R., Mukhamadiev N. K. Sorption characteristics of mesoporous composite SiO2· TiO2 // Central asian journal of medical and natural sciences. – 2021. – V. 2. – №. 5. – P. 494-498.
Uzokov J.R., Mukhamadiev N.K. Synthesis of mesopore SiO2 ∙xZrO2 nanocomposite sorbents and their texture characteristics // Scientific bulletin of Samarkand State University-2021. Special issue. Sol-gel 2020 International Conference set of materials -2021.-V. №. 4. – P. 32-33.
Uzokov J.R., Muhamadiyev N.K. Synthesis of nanosorbents for chromatography from tetraethoxysilane and metal oxides // Proceedings of the international scientific-practical conference “Achievements, problems and prospects of complex innovative development of the Zarafshan oasis” Navoiy-2019. P. – 366-368.
Uzokov J.R., Mukhamadiev N.K. Sorption Characteristics of the mesoporous sorbents based on tetraethoxysilane and titanium oxide //European journal of molecular and clinical medicine. – 2020. – V. 7.– №. 7. – P. 656-660
Nturanabo F., Masu L., Kirabira J. B. Novel applications of aluminium metal matrix composites //Aluminium Alloys and Composites. – 2019.
Khodakarami M., Bagheri M. Recent advances in synthesis and application of polymer nanocomposites for water and wastewater treatment //Journal of Cleaner Production. – 2021. – Т. 296. – С. 126404.
He Y. He, J., Wang L., Yu Z., Zhang H., Liu Y., Lei,B.Synthesis of double carbon dots co-doped mesoporous Al2O3 for ratiometric fluorescent determination of oxygen //Sensors and Actuators B: Chemical. – 2017. – Т. 251. – С. 918-926.
Wu Z., Q., Feng D., Webley P. A., Zhao D. Ordered mesoporous crystalline γ-Al2O3 with variable architecture and porosity from a single hard template //Journal of the American Chemical Society. – 2010. – Т. 132. – №. 34. – С. 12042-12050.
Fayomi O. S. I., Babaremu K. O., Akande I. G. Impact of Al-Composites in the Manufacturing Industry: A Neccessity //International Journal of Civil Engineering and Technology. – 2019. – Т. 10. – №. 3.
Szczęśniak B. Babaremu K. O., Akande I. G. Mechanochemical synthesis of highly porous materials //Materials Horizons. – 2020. – Т. 7. – №. 6. – С. 1457-1473.
Xifre-Perez Mesoporous alumina as a biomaterial for biomedical applications //Open Material Sciences. – 2015. – Т. 2. – №. 1. – С. 13-32.
Naik B., Ghosh N. N. A review on chemical methodologies for preparation of mesoporous silica and alumina based materials //Recent patents on nanotechnology. – 2009. – Т. 3. – №. 3. – С. 213-224.
Griffin, Sharoon, "Natural nanoparticles: a particular matter inspired by nature." Antioxidants 7.1 (2017): 3.
Wei, Jing, "Ordered mesoporous alumina with ultra-large pores as an efficient absorbent for selective bioenrichment." Chemistry of Materials 29.5 (2017): 2211-2217.
Wu, Y. S., Ma, J., Li, M. C., & Hu, F. (2013). Synthesis of γ-Al2O3 with high surface area and large pore volume by reverse precipitation-azeotropic distillation method. Chemical Research in Chinese Universities, 29(2), 206-209.
Wu, Yu-sheng, Jiao Ma, Ming-chun Li, and Fang Hu. "Synthesis of γ-Al2O3 with high surface area and large pore volume by reverse precipitation-azeotropic distillation method." Chemical Research in Chinese Universities 29, no. 2 (2013): 206-209.
Said, S., S. Mikhail, and M. Riad. "Recent processes for the production of alumina nano-particles." Materials Science for Energy Technologies 3 (2020): 344-363.
Sayed, E., Haj-Ahmad, R., Ruparelia, K., Arshad, M. S., Chang, M. W., & Ahmad, Z. (2017). Porous inorganic drug delivery systems—a review. Aaps Pharmscitech, 18(5), 1507-1525.
Toberer, E.S. and Seshadri, R., 2006. Template-free routes to porous inorganic materials. Chemical communications, (30), pp.3159-3165.
Ghanizadeh, S., Bao, X., Vaidhyanathan, B., & Binner, J. (2014). Synthesis of nano α-alumina powders using hydrothermal and precipitation routes: a comparative study. Ceramics International, 40(1), 1311-1319.
Yang, Yanping, Kunming Pan, Shizhong Wei, Wuhui Li, Liujie Xu, Jiwen Li, Fangnao Xiao et al. "Hydrothermal synthesis and adsorption property of porous spherical Al2O3 nanoparticles." Materials Research Express 6, no. 7 (2019): 075023.
Gaweł, Bartłomiej, Kamila Gaweł, and Gisle Øye. "Sol-gel synthesis of non-silica monolithic materials." Materials 3.4 (2010): 2815-2833.
Moein, Mohammad Mahdi, Abbi Abdel-Rehim, and Mohamed Abdel-Rehim. "Recent applications of molecularly imprinted sol-gel methodology in sample preparation." Molecules 24, no. 16 (2019): 2889.
Feinle, Andrea, Michael S. Elsaesser, and Nicola Huesing. "Sol–gel synthesis of monolithic materials with hierarchical porosity." Chemical Society Reviews 45, no. 12 (2016): 3377-3399.
Colleoni, Claudio. "Sol-gel synthesis and hybrid thin film deposition for innovative textile finishing. Study, characterization and environmental impact evaluation." (2012).
Uzokov J. R., Mukhamadiev N. K. Sorption characteristics of mesoporous composite SiO2· TiO2 // Central asian journal of medical and natural sciences. – 2021. – V. 2. – №. 5. – P. 494-498.
Uzokov J.R., Mukhamadiev N.K. Synthesis of mesopore SiO2 ∙xZrO2 nanocomposite sorbents and their texture characteristics // Scientific bulletin of Samarkand State University-2021. Special issue. Sol-gel 2020 International Conference set of materials -2021.-V. №. 4. – P. 32-33.
Uzokov J.R., Muhamadiyev N.K. Synthesis of nanosorbents for chromatography from tetraethoxysilane and metal oxides // Proceedings of the international scientific-practical conference “Achievements, problems and prospects of complex innovative development of the Zarafshan oasis” Navoiy-2019. P. – 366-368.
Uzokov J.R., Mukhamadiev N.K. Sorption Characteristics of the mesoporous sorbents based on tetraethoxysilane and titanium oxide //European journal of molecular and clinical medicine. – 2020. – V. 7.– №. 7. – P. 656-660
Published
2022-05-28
How to Cite
Diyarov A.A., Mukhamadiev N.Q., Sayitkulov Sh.M., & Uzokov J.R. (2022). Synthesis of mesoporous sorbents on the basis of Al2O3 and their textural characteristics. Central Asian Journal of Medical and Natural Science, 3(3), 511-518. Retrieved from https://cajmns.centralasianstudies.org/index.php/CAJMNS/article/view/817
Issue
Section
Articles
