Immobilized Organic Luminescent Reagents for the Determination of Certain Heavy Metals
Keywords:
immobilization, toxic metals, organic compounds, sorption-luminescent determination
Abstract
Luminescent reagents for the determination of aluminum, beryllium, zinc, tungsten, thorium, and lead are proposed. Completed immobilization investigated organic compounds and a positive effect is shown on their chemical and analytical properties. New organic reagent-carrier systems for solid-phase luminescent determination of aluminum, beryllium, zinc, tungsten, thorium, and lead are proposed. Highly sensitive and selective methods of sorption-luminescent determination of the studied metals in environmental objects have been developed.
References
1. Medvedev I. F., Derevyagin S. S. Heavy metals in ecosystems / Saratov: "Rakurs", 2017. - 178 p.
2. Savvin S. B., Kuznetsov V. V., Sheremetyev S. V., Mikhailova A.V. Optical chemical sensors (micro-and nanosystems) for liquid analysis // Russian Chemical Industry – 2008. – T.LII. – № 2. – P. 7-16.
3. Gavrilenko N. A., Saranchina N. V., Gavrilenko M. A.Solid-phase spectrophotometric determination of selenium (IV) using dithizone immobilized in a polymethacrylate matrix, Analitika i kontrol–, 2014. – Vol. 18. - No. 4. – C.424-429.
4. Madusmanova N.K., Smanova Z.A., Zhuraev I.I. Properties of the New Analytical Reagent 2-Hydroxy-3-Nitrosonaphthaldehyde// Journal of Analytical Chemistry, 2020, 75 (1), pp. 135-138.
5. Akhmetshina A. I., Davletbaev R. S., Davletbayeva I. M., et al. Immobilization of organic reagents on optically transparent mesoporous polymers and their analytical use // Housing and utilities sector. – 2015. – T. 88. – №3. – P. 490-496.
6. Romanovskaya G. I. Razvitie metodov luminescentnogo analiza v Rossii za dvadtsatiye let [Development of methods of luminescent analysis in Russia for twenty years]. analyte. chemistry. -2011. - Vol. 66. - No. 11. - pp. 1157-1163.
7. Shvoeva O. P., Dedkova V. P., Savvin S. B. Sorption-spectroscopic and test methods for uranium determination (VI) and iron (III) from a single solid-phase sample of a fibrous material filled with an AB-17 ion exchanger. chemistry. – 2013. – Vol. 68. - No. 10. – P. 975-979.
8. Losev V. N., Didukh S. L., Mukhina A. N., Trofimchuk A. K. Application of silica modified with polyhexamethylene guanidine and nitroso-p salt for concentration and determination of cobalt // Journal. analyte. chemistry. – 2015. – Vol. 70. – №6. – Pp. 594-601.
9. Nurmukhammadov Zh.Sh., Smanova Z.A., Tadzhimukhamedov Kh.S., Inatova M.S. Synthesis and properties of a new analytical reagent, 2-hydroxy-3- nitrosonaphthalene-1-carbaldehyde // Russian Journal of Organic Chemistry, 2014, 50(6), стр. 895–897.
10. Zeltser L. E. Vereshchagina N. B., Arkhipova A. A., Bychenko A.V. Determination of iron (III) by solid-phase spectroscopy using immobilized chromazurol. analyte. chemistry. -1995. - T. 50. - No. 9. - pp. 850-854.
11. Zaporozhets O. A., Gaver O. M., Sukhan V. V. Immobilization of analytical reagents on the surface of carriers. // Usp. chem. -1997. - Vol. 66. - No. 7. - pp. 702-712.
12. Savvin S. B., Dedkova V. P., Shvoeva O. P. Sorption-spectroscopic and test methods for determining metal ions on the solid phase of ion-exchange materials / / Usp. chem. - 2000. - vol. 69. - No. 3. - pp. 203-217;
13. Marie Pospíšilová, Gabriela Kuncová and Josef Trögl. Fiber-Optic Chemical Sensors and Fiber-Optic Bio-Sensors // Sensors. – 2015. – Vol.15. – P. 25208-25259.
14. Mirsad Salkic. Spectrophotometric determination of L-ascorbic acid based on its oxidation by potassium peroxodisulfate in the presence of Cu(II) as catalyst // Journal of Analytical Chemistry. -2016. - V. 71. - No. 2. - pp. 159-163.
15. Didukh-Shadrina S. L., Losev V. N., Maznyak N. V., Trofimchuk Application of silica with immobilized 2-nitroso-1-naphthol-4-sulfonic acid for sorption-photometric determination of palladium. chemistry. -2019. - Vol. 74. - No. 7. - pp. 574-579.
16. Losev V. N., Metelitsa S. I. Sorption-luminescent determination of aluminum using silica modified with polyhexamethylene guanidine and 8-hydroxyquinoline-5-sulfonic acid Siberian Federal University. Series: Chemistry. – 2009. – T.2. – №3. – With. 246-253.
17. Agnieszka Zuber, Malcolm Purdey, Erik Schartner, Caroline Forbes Benjaminvan der Hoek and etc. Detection of gold nanoparticles with different sizes using absorption and fluorescence based method // Sensors and Actuators B: Chemical. – May 2016. – Vol. 227. – P.117-127.
18. Andrey A. Leonov, Alexander A. Sergeev, Alexander Yu. Mironenko, Sergey S. Voznesenskiy. Luminescent chemosensor systems for detecting metal ions in aqueous media //J of Biomedical Photonics and Eng. -2018. -V. 4. -№ 1. -R.10502-1 - 10502-6.
19. Usmanova Kh. U., Smanova Z. A. Sorption-luminescent determination of some heavy metals using immobilized morin // Doklady Akademii nauk Respubliki Uzbekistan. Tashkent, No. 6, 2016, pp. 59-61.
20. Zeltser L. E., Korenman Ya. I., Arkhipova L. A., Vereshchagina N. G., Bychenko A.V. Immobilized 8-hydroxyquinoline as a sensitive sensor component for the determination of aluminum ions. -1995. - Volume 68. issue 7. C.1107-1110.
21. Usmanova H.At., Bobozhonov H.Sh., Smanova З.But. Sensitive layers for optical sensory devices for aluminum. // International Journal of Psychosocial Rehabilitation, Vol. 24, № 08. 2020. P. 5817-5822.
22. Korenman I. M. Organicheskie reagenty v neorganicheskom analiz [Organic reagents in inorganic analysis]. Moscow: Khimiya, -1980, -448 p.
23. Degtev M. I. Organic reagents and their complex compounds. Study. The manual. (Perm State University) 2nd ed. reprint. Perm.: PSU, -2009. -269 p.
24. Usmanova Kh. U., Smanova Z. A. Sorption-luminescent determination of zinc in environmental objects / / "Science and world", International scientific journal No. 2 (30). - 2016, Vol. I. - p. 103-104.
25. Korostylev P. P. Prepotovlenie rastvorov dlya khimiko-analiticheskikh rabot [Preparation of solutions for chemical and analytical works]. -1981. - 202 p.
26. Weisberg M, Proskauer E, Rydberg J, Stibs 3. Organic solvents, Moscow: Inostr.lit. -1958. - p. 120-145.
27. Leo M. L. Nollet. Water analysis handbook. SPb.: Profe6russia. -2012. -919 p.
28. Usmanova Kh. U., Smanova Z. A. Sorption-luminescent determination of some heavy metals using immobilized morin // Doklady Akademii nauk Respubliki Uzbekistan. -2016. - No. 6. - pp. 59-61.
29. Qutlimurotova N., Mahmadoliev S., Smanova Z., Yakhshiyeva Z., Tursunkulov Z. Amperometric determination of cerium (III) using 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid solution// Periodico Tche Quimica, 2020, 17 (36), pp. 735-749.
30. Ashirov M.A., Yangibaev A.E., Khalilova L.M., Smanova Z.A. Spectrophotometric Determination of Mercury Ions with the New Reagent N-Methylanabazin-Α-Azo-1,8-Aminonaphthol-4,6-Disulfonic Acid. International Journal of Emerging Trends in Engineering Research. 2020. V.8. №.9. P. 5413-5418.
31. Smanova Z. A., Usmanova Kh. U. Immobilization of oxyazo compounds to improve metrological parameters of sorption-spectroscopic determination of some metals / / Uzbek Chemical Journal, 2018, no 3, pp. 89-95.
2. Savvin S. B., Kuznetsov V. V., Sheremetyev S. V., Mikhailova A.V. Optical chemical sensors (micro-and nanosystems) for liquid analysis // Russian Chemical Industry – 2008. – T.LII. – № 2. – P. 7-16.
3. Gavrilenko N. A., Saranchina N. V., Gavrilenko M. A.Solid-phase spectrophotometric determination of selenium (IV) using dithizone immobilized in a polymethacrylate matrix, Analitika i kontrol–, 2014. – Vol. 18. - No. 4. – C.424-429.
4. Madusmanova N.K., Smanova Z.A., Zhuraev I.I. Properties of the New Analytical Reagent 2-Hydroxy-3-Nitrosonaphthaldehyde// Journal of Analytical Chemistry, 2020, 75 (1), pp. 135-138.
5. Akhmetshina A. I., Davletbaev R. S., Davletbayeva I. M., et al. Immobilization of organic reagents on optically transparent mesoporous polymers and their analytical use // Housing and utilities sector. – 2015. – T. 88. – №3. – P. 490-496.
6. Romanovskaya G. I. Razvitie metodov luminescentnogo analiza v Rossii za dvadtsatiye let [Development of methods of luminescent analysis in Russia for twenty years]. analyte. chemistry. -2011. - Vol. 66. - No. 11. - pp. 1157-1163.
7. Shvoeva O. P., Dedkova V. P., Savvin S. B. Sorption-spectroscopic and test methods for uranium determination (VI) and iron (III) from a single solid-phase sample of a fibrous material filled with an AB-17 ion exchanger. chemistry. – 2013. – Vol. 68. - No. 10. – P. 975-979.
8. Losev V. N., Didukh S. L., Mukhina A. N., Trofimchuk A. K. Application of silica modified with polyhexamethylene guanidine and nitroso-p salt for concentration and determination of cobalt // Journal. analyte. chemistry. – 2015. – Vol. 70. – №6. – Pp. 594-601.
9. Nurmukhammadov Zh.Sh., Smanova Z.A., Tadzhimukhamedov Kh.S., Inatova M.S. Synthesis and properties of a new analytical reagent, 2-hydroxy-3- nitrosonaphthalene-1-carbaldehyde // Russian Journal of Organic Chemistry, 2014, 50(6), стр. 895–897.
10. Zeltser L. E. Vereshchagina N. B., Arkhipova A. A., Bychenko A.V. Determination of iron (III) by solid-phase spectroscopy using immobilized chromazurol. analyte. chemistry. -1995. - T. 50. - No. 9. - pp. 850-854.
11. Zaporozhets O. A., Gaver O. M., Sukhan V. V. Immobilization of analytical reagents on the surface of carriers. // Usp. chem. -1997. - Vol. 66. - No. 7. - pp. 702-712.
12. Savvin S. B., Dedkova V. P., Shvoeva O. P. Sorption-spectroscopic and test methods for determining metal ions on the solid phase of ion-exchange materials / / Usp. chem. - 2000. - vol. 69. - No. 3. - pp. 203-217;
13. Marie Pospíšilová, Gabriela Kuncová and Josef Trögl. Fiber-Optic Chemical Sensors and Fiber-Optic Bio-Sensors // Sensors. – 2015. – Vol.15. – P. 25208-25259.
14. Mirsad Salkic. Spectrophotometric determination of L-ascorbic acid based on its oxidation by potassium peroxodisulfate in the presence of Cu(II) as catalyst // Journal of Analytical Chemistry. -2016. - V. 71. - No. 2. - pp. 159-163.
15. Didukh-Shadrina S. L., Losev V. N., Maznyak N. V., Trofimchuk Application of silica with immobilized 2-nitroso-1-naphthol-4-sulfonic acid for sorption-photometric determination of palladium. chemistry. -2019. - Vol. 74. - No. 7. - pp. 574-579.
16. Losev V. N., Metelitsa S. I. Sorption-luminescent determination of aluminum using silica modified with polyhexamethylene guanidine and 8-hydroxyquinoline-5-sulfonic acid Siberian Federal University. Series: Chemistry. – 2009. – T.2. – №3. – With. 246-253.
17. Agnieszka Zuber, Malcolm Purdey, Erik Schartner, Caroline Forbes Benjaminvan der Hoek and etc. Detection of gold nanoparticles with different sizes using absorption and fluorescence based method // Sensors and Actuators B: Chemical. – May 2016. – Vol. 227. – P.117-127.
18. Andrey A. Leonov, Alexander A. Sergeev, Alexander Yu. Mironenko, Sergey S. Voznesenskiy. Luminescent chemosensor systems for detecting metal ions in aqueous media //J of Biomedical Photonics and Eng. -2018. -V. 4. -№ 1. -R.10502-1 - 10502-6.
19. Usmanova Kh. U., Smanova Z. A. Sorption-luminescent determination of some heavy metals using immobilized morin // Doklady Akademii nauk Respubliki Uzbekistan. Tashkent, No. 6, 2016, pp. 59-61.
20. Zeltser L. E., Korenman Ya. I., Arkhipova L. A., Vereshchagina N. G., Bychenko A.V. Immobilized 8-hydroxyquinoline as a sensitive sensor component for the determination of aluminum ions. -1995. - Volume 68. issue 7. C.1107-1110.
21. Usmanova H.At., Bobozhonov H.Sh., Smanova З.But. Sensitive layers for optical sensory devices for aluminum. // International Journal of Psychosocial Rehabilitation, Vol. 24, № 08. 2020. P. 5817-5822.
22. Korenman I. M. Organicheskie reagenty v neorganicheskom analiz [Organic reagents in inorganic analysis]. Moscow: Khimiya, -1980, -448 p.
23. Degtev M. I. Organic reagents and their complex compounds. Study. The manual. (Perm State University) 2nd ed. reprint. Perm.: PSU, -2009. -269 p.
24. Usmanova Kh. U., Smanova Z. A. Sorption-luminescent determination of zinc in environmental objects / / "Science and world", International scientific journal No. 2 (30). - 2016, Vol. I. - p. 103-104.
25. Korostylev P. P. Prepotovlenie rastvorov dlya khimiko-analiticheskikh rabot [Preparation of solutions for chemical and analytical works]. -1981. - 202 p.
26. Weisberg M, Proskauer E, Rydberg J, Stibs 3. Organic solvents, Moscow: Inostr.lit. -1958. - p. 120-145.
27. Leo M. L. Nollet. Water analysis handbook. SPb.: Profe6russia. -2012. -919 p.
28. Usmanova Kh. U., Smanova Z. A. Sorption-luminescent determination of some heavy metals using immobilized morin // Doklady Akademii nauk Respubliki Uzbekistan. -2016. - No. 6. - pp. 59-61.
29. Qutlimurotova N., Mahmadoliev S., Smanova Z., Yakhshiyeva Z., Tursunkulov Z. Amperometric determination of cerium (III) using 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid solution// Periodico Tche Quimica, 2020, 17 (36), pp. 735-749.
30. Ashirov M.A., Yangibaev A.E., Khalilova L.M., Smanova Z.A. Spectrophotometric Determination of Mercury Ions with the New Reagent N-Methylanabazin-Α-Azo-1,8-Aminonaphthol-4,6-Disulfonic Acid. International Journal of Emerging Trends in Engineering Research. 2020. V.8. №.9. P. 5413-5418.
31. Smanova Z. A., Usmanova Kh. U. Immobilization of oxyazo compounds to improve metrological parameters of sorption-spectroscopic determination of some metals / / Uzbek Chemical Journal, 2018, no 3, pp. 89-95.
Published
2022-06-08
How to Cite
Usmanova, H. U., Bobomurodova, M. S., & Smanova, Z. A. (2022). Immobilized Organic Luminescent Reagents for the Determination of Certain Heavy Metals. Central Asian Journal of Medical and Natural Science, 3(3), 398-407. https://doi.org/10.17605/cajmns.v3i3.801
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