Synthesis of Polyoxide Catalysts and their Application Possibility in Catalytic Conversion of Methane
Abstract
The research is dedicated to the study of the conversion of methane with carbon dioxide using the catalysts containing NiO. The composites of oxides of the d-metals – catalysts that were prepared by the method of Solution-combustion synthesis using sol-gel technology is the object of the research. The morphology of the catalysts surface has been investigated by electronic microscopy (SEM), the phase composition by X-ray diffractometry (XRD), the element composition by X-ray microanalysis, the texture characteristics by McBen-Bakra mercury porometry. According to the results it was identified that the catalysts are high dispersed compounds, which composed of oxides of Ni, Al, Zr and Ti. The specific surface area of the polyoxide catalysts was determined to be SBET=420 ÷ 598 m2/g, the specific volume of the pores Vs=0,74 ÷ 0,92 cm3/g, the average diameter of pores D=220 ÷ 355 nm, the monolayer capacity am=1,5 ÷ 0,96 mole/kg and the adsorption saturation as =5,4 ÷ 2.2 moles/kg. Also, the catalytic activity of the catalysts was estimated by the carbonate conversion of methane. In this case the conversion of methane was 92%, carbon dioxide 87%, the yield of formed CO and H2 was 57,6 % and 51,9 % respectively.
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