Cu3BiS3 Nanocomposites for Optoelectronics and NO2 gas Sensing

Hoolya  Nadhim Nooruldeen; Mohanad  Qader Kareem

Hoolya Nadhim Nooruldeen Department of Physics, College of Science, University of Kirkuk, Kirkuk, Iraq.
Mohanad Qader Kareem Department of Physics, College of Science, University of Kirkuk, Kirkuk, Iraq.

Keywords: Cu3BiS3 nanocomposites; Optoelectronic materials; NO2 gas sensing; Nanostructured semiconductors; Chalcogenide-based sensors.

Abstract

This paper focuses on Cu3BiS3 nanocomposites that were produced using solvothermal technique in the presence of a capping agent known as Mercaptoacetic acid (MMA). The study also shows that these nanostructures have the possibility of being used in optoelectronic and gas sensing industries. FE-SEM analysis, XRD diffraction pattern, and UV-Vis spectroscopy reveal regular nanostructures with crystalline nature and the ability to control their optical features. Electrical measurements show promising PIV performance and temperature-dependent Hall Effect measurements provide information about main charge transport channels. The study of the dynamic response of the nanocomposite to NO2 is performed through dynamic response curves as a function of operating temperature and shows a more detailed and richer interdependence between operating temperature and sensing performance. Interestingly, the sensitivity is maximized at 100°C which is a remarkable improvement in the development of the room-temperature gas detecting device. This work expands the knowledge on ternary chalcogenide nanocomposites and suggests ways in which they can be implemented in future optoelectronic and environmental applications. This systematic study helps in understanding the structural, optical, electrical and gas sensing characteristics of Cu3BiS3 nanocomposites for various technological applications.

References

Y. Khan, H. Sadia, S.Z. Ali Shah, M.N. Khan, A.A. Shah, N. Ullah, M.F. Ullah, H. Bibi, O.T. Bafakeeh, N. Ben Khedher, S.M. Eldin, B.M. Fadhl, M.I. Khan, Classification, Synthetic, and Characterization Approaches to Nanoparticles, and Their Applications in Various Fields of Nanotechnology: A Review, Catalysts. 12 (2022). https://doi.org/10.3390/catal12111386.

Y. Yang, C. Liu, Y. Wang, J. Hao, Nanorods Assembled Hierarchical Bi2S3 for Highly Sensitive Detection of Trace NO2 at Room Temperature, Chemosensors. 12 (2024). https://doi.org/10.3390/chemosensors12010008.

P.Shankar, J. Bosco, B. Rayappan , Gas sensing mechanism of metal oxides: The role of ambient atmosphere, type of semiconductor and gases - A review, Sci. Lett. J.4, 126 (2015).

G. Kunakova, R. Meija, I. Bite, J. Prikulis, J. Kosmaca, J. Varghese, J.D. Holmes, D. Erts, Sensing properties of assembled Bi2S3 nanowire arrays, Phys. Scr. 90 (2015). https://doi.org/10.1088/0031-8949/90/9/094017.

T.Wang et-al , Bifunctional gas sensor based on Bi2S3/SnS2 heterostructures with improved selectivity through visible light modulation . j.Materials Chemistry A, Issue 8 , 28 February (2022). DOI: 10.1039/D1TA10461F.

J. Fonollosa, A. Solórzano, S. Marco, Chemical sensor systems and associated algorithms for fire detection: A review, Sensors (Switzerland). 18 (2018). https://doi.org/10.3390/s18020553.

Rath-et-al , Solution-Processable Cu3BiS3 Thin Films: Growth Process Insightsand Increased Charge Generation Properties by Interface. ACS Appl. Mater. Interfaces 2023, 15, 41624−41633. https://doi.org/10.1021/acsami.3c10297.

W.Wei et - al , Enhanced Thermoelectric Properties of Hydrothermal Synthesized BiCl3/Bi2S3 Composites. Journal of Inorganic Materials , Vol. 34 No. 3 (2019). DOI: 10.15541/jim20180261.

A. Hosen, M.S. Mian, S.R. Al Ahmed, Simulating the performance of a highly efficient CuBi2O4-based thin-film solar cell, SN Appl. Sci. 3 (2021). https://doi.org/10.1007/s42452-021-04554-z.

T. Varghese, C. Dun, N. Kempf, M. Saeidi‐Javash, C. Karthik, J. Richardson, C. Hollar, D. Estrada, Y. Zhang, Flexible Thermoelectric Devices of Ultrahigh Power Factor by Scalable Printing and Interface Engineering, Adv. Funct. Mater. 30 (2020) 1905796. https://doi.org/10.1002/adfm.201905796.

A.P. Gonçalves, E.B. Lopes, J. Monnier, J. Bourgon, J.B. Vaney, A. Piarristeguy, A. Pradel, B. Lenoir, G. Delaizir, M.F.C. Pereira, E. Alleno, C. Godart, Fast and scalable preparation of tetrahedrite for thermoelectrics via glass crystallization, J. Alloys Compd. 664 (2016) 209–217. https://doi.org/10.1016/j.jallcom.2015.12.213.

Y. Zhao, X. Zhu, Y. Huang, S. Wang, J. Yang, Y. Xie, Synthesis, growth mechanism, and work function at highly oriented {001} surfaces of bismuth sulfide microbelts, J. Phys. Chem. C. 111 (2007) 12145–12148.

P. Song, Y. Yang, F. Li, H. Yu, X. Dong, T. Wang, Rapid and highly sensitive detection of formaldehyde gas via a polyoxometalate–CuBi 2 O 4 composite gas sensor , Polyoxometalates. 3 (2024) 9140053. https://doi.org/10.26599/pom.2024.9140053.

Tarek S. Jamil et- al , The synthesis of nano-sized undoped, Bi doped and Bi, Cu co doped SrTiO3 using two solegel methods to enhance the photocatalytic performance for the degradation of dibutyl phthalate under visible light. C. R. Chimie 20 (2017) 97-106 .http://dx.doi.org/10.1016/j.crci.2016.05.022.

Y. Jian et-al , Gas Sensors Based on Chemi‑Resistive Hybrid Functional Nanomaterials Nano-Micro Lett. (2020) 12:71 . https://doi.org/10.1007/s40820-020-0407-5

Mohanad Q. Kareem, M.M. Ameen, S.A. Hassan, S.M. Shareef., Synthesis of Tetrahedrite Zincian Nanocomposites via solvothermal process at low temperature, 20 (2024) 40005–40013. https://doi.org/10.1016/j.ceramint.2024.07.385. University of Kirkuk.

M.Q. Kareem, N.K. Hassan, Evaluation of Williamson–Hall strain and Electrical properties in WO3@ NaDCC/ITO nanoparticles thin films prepared by Hydrothermal method,IJRTEM , 3(6) 16-26 (2019). University of Kirkuk.

K.R. Khedir, Z.S. Saifaldeen, T. Demirkan, R.B. Abdulrahman, T. Karabacak, Growth of zinc oxide nanorod and nanoflower structures by facile treatment of zinc thin films in boiling de-ionized water, J. Nanosci. Nanotechnol. 17 (2017) 4842–4850. https://doi.org/10.1166/jnn.2017.13432.

M.Q. Kareem, N.K. Hassan, Utilization and measurements of WO3/ITO &Novel WO3@ NaDCC/ITO thin films prepared by Hydrothermal method as a Nitride Dioxide .IJMREM , 2(8) 26-33 (2019). University of Kirkuk.