Investigating the Concentration of Heavy Elements in Soils from Thi-Qar Governorate

  • Alaa M. Nassar General Directorate of Education in Thi-Qar, Ministry of Education, Iraq
Keywords: heavy metals, soil pollution, anthropogenic activities

Abstract

Heavy metals are widely recognized as environmental contaminants owing to their toxicity, enduring presence in the environment, and ability to accumulate in living organisms. These metals originate from natural sources such as the breakdown of rocks containing metal deposits and volcanic eruptions. However, human activities such as transportation, waste management, industrial development, and various social and agricultural practices greatly contribute to environmental pollution and affect the overall global ecosystem. Heavy metals (HMs) are among the most dangerous toxicants because they enter the soil via multiple mechanisms and accumulate in the food chain. Toxic metal pollution has increased dramatically from the beginning of the industrial revolution. This study was conducted to determine the levels of contamination of the soil of Thi Qar Governorate, located in southern Iraq, with heavy metals including lead, cadmium, Zinc, and copper during September and October for the years 2023-2024. The study contained modelling and analysis of nine soil samples from the Eredo, Al-Husaynat, Al-Arja, Al-Khamisiya Al-Bathaa, Suq Al-Shuyoukh, Al-Shatrah, Al-Rifai, and Al-Chibaish districts. The heavy metal measurement levels were in the following range: Pb (73 -2.5 ppm), Cd (13.3-0.016 ppm), Zn (42-8.1 ppm), and Cu (26-4 ppm). The concentration of the metals in the soil samples varied according to the following trend: Pb>Zn>Cu>Cd. The findings indicated that the soil in the Eredo area, Al-Arja, and Al-Husaynat districts is contaminated with lead and cadmium, exceeding the globally permitted limits for uncontaminated soil.

References

H. K. Okoro, O. S. Fatoki, F. A. Adekola, B. J. Ximba, and ..., A review of sequential extraction procedures for heavy metals speciation in soil and sediments. digitalknowledge.cput.ac.za, 2012. [Online]. Available: https://digitalknowledge.cput.ac.za/handle/11189/3650

F. X. Han, A. Banin, Y. Su, D. L. Monts, J. M. Plodinec, and ..., “Industrial age anthropogenic inputs of heavy metals into the pedosphere,” …, 2002, doi: 10.1007/s00114-002-0373-4.

M. R. G. Sayyed and M. H. Sayadi, “Variations in the heavy metal accumulations within the surface soils from the Chitgar industrial area of Tehran,” … of the International Academy of Ecology …, 2011, [Online]. Available: https://www.academia.edu/download/92097703/Variations-in-the-heavy-metal-accumulations.pdf

K. V Raju, R. K. Somashekar, and K. L. Prakash, “Spatio-temporal variation of heavy metals in Cauvery River basin,” Proceedings of the International …, 2013, [Online]. Available: http://www.iaees.org/publications/journals/piaees/articles/2013-3(1)/spatio-temporal-variation-of-heavy-metals.pdf

S. R. Jean-Philippe, N. Labbé, J. A. Franklin, and ..., “Detection of mercury and other metals in mercury contaminated soils using mid-infrared spectroscopy,” Proceedings of the …, 2012, [Online]. Available: http://www.iaees.org/publications/journals/piaees/articles/2012-2(3)/detection-of-mercury-and-other-metals.pdf

S. K. Prajapati, “Heavy metal speciation of soil and Calotropis procera from thermal power plant area,” Proceedings of the international Academy of Ecology …, 2014, [Online]. Available: http://www.iaees.org/publications/journals/piaees/articles/2014-4(2)/heavy-metal-speciation-of-soil.pdf

M. H. Sayadi, “Impact of land use on the distribution of toxic metals in surface soils in Birjand city, Iran,” Proceedings of the international Academy of Ecology …, 2014, [Online]. Available: http://www.iaees.org/publications/journals/piaees/articles/2014-4(1)/impact-of-land-use-on-distribution-of-toxic-metals.pdf

F. Zojaji, “Bioaccumulation of chromium by Zea mays in wastewater-irrigated soil: An experimental study,” Proceedings of the International Academy of Ecology …, 2014, [Online]. Available: http://www.iaees.org/publications/journals/piaees/articles/2014-4(2)/bioaccumulation-of-chromium-by-Zea-mays.pdf

S. Bakshi, C. Banik, and H. Z. L. H. ZhenLi, The impact of heavy metal contamination on soil health. cabidigitallibrary.org, 2018. doi: 10.5555/20183271063.

A. Kabata-Pendias, Trace elements in soils and plants. taylorfrancis.com, 2000. doi: 10.1201/9781420039900.

R. L. Bansal, V. K. Nayar, and P. N. Takkar, “Effect of heavy metals on soil horizon,” J. Indian Soc, vol. 40, pp. 794–796, 1992.

S. C. Wong, X. D. Li, G. Zhang, S. H. Qi, and Y. S. Min, “Heavy metals in agricultural soils of the Pearl River Delta, South China,” Environmental pollution, 2002, [Online]. Available: https://www.sciencedirect.com/science/article/pii/S0269749101003256

D. R. Jackson and A. P. Watson, “Disruption of Nutrient Pools and Transport of Heavy Metals in a Forested Watershed Near a Lead Smelter,” J Environ Qual, vol. 6, no. 4, pp. 331–332, 1977.

A. Alwan, “Measuring the concentration of heavy elements Pb, Cd, Ni and uranium in the Soil of Some areas in Baghdad,” University of Baghdad, 2009.

F. J. Bris, S. Garnaud, N. Apperry, A. Gonzalez, and ..., “A street deposit sampling method for metal and hydrocarbon contamination assessment,” Science of the total …, 1999, [Online]. Available: https://www.sciencedirect.com/science/article/pii/S0048969799001928

W. L. Lindsay, J. F. Hodgson, and W. A. Norvell, The physico-chemical equilibrium of metal chelates in soils and their influence on the availability of micronutrient cations. cabidigitallibrary.org, 1967. doi: 10.5555/19671904472.

C. Baird, “Environment Chemistry ,” University of Western Ontario, New York, 2001.

L. Järup, “Hazards of heavy metal contamination,” Br Med Bull, 2003, [Online]. Available: https://academic.oup.com/bmb/article-abstract/68/1/167/421303

G. Nabulo, S. D. Young, and C. R. Black, “Assessing risk to human health from tropical leafy vegetables grown on contaminated urban soils,” Science of the Total Environment, 2010, [Online]. Available: https://www.sciencedirect.com/science/article/pii/S004896971000639X

A. Baba and O. Deniz, “Effect of warfare waste on soil: a case study of Gallipoli Peninsula (Turkey),” International Journal of Environment and …, 2004, doi: 10.1504/IJEP.2004.006056.

M. Saunois, “The global methane budget 2000-2017,” Earth Syst Sci Data, vol. 12, no. 3, pp. 1561–1623, 2020, doi: 10.5194/essd-12-1561-2020.

M. Crippa, “Food systems are responsible for a third of global anthropogenic GHG emissions,” Nat Food, vol. 2, no. 3, pp. 198–209, 2021, doi: 10.1038/s43016-021-00225-9.

A. Yan, “Phytoremediation: A Promising Approach for Revegetation of Heavy Metal-Polluted Land,” Front Plant Sci, vol. 11, 2020, doi: 10.3389/fpls.2020.00359.

J. Briffa, “Heavy metal pollution in the environment and their toxicological effects on humans,” Heliyon, vol. 6, no. 9, 2020, doi: 10.1016/j.heliyon.2020.e04691.

S. Piao, “Characteristics, drivers and feedbacks of global greening,” Nat Rev Earth Environ, vol. 1, no. 1, pp. 14–27, 2020, doi: 10.1038/s43017-019-0001-x.

S. Sharma, “Effect of restricted emissions during COVID-19 on air quality in India,” Science of the Total Environment, vol. 728, 2020, doi: 10.1016/j.scitotenv.2020.138878.

K. N. Palansooriya, “Soil amendments for immobilization of potentially toxic elements in contaminated soils: A critical review,” Environ Int, vol. 134, 2020, doi: 10.1016/j.envint.2019.105046.

Z. Gong, “Plant abiotic stress response and nutrient use efficiency,” Sci China Life Sci, vol. 63, no. 5, pp. 635–674, 2020, doi: 10.1007/s11427-020-1683-x.

A. Alengebawy, “Heavy metals and pesticides toxicity in agricultural soil and plants: Ecological risks and human health implications,” Toxics, vol. 9, no. 3, pp. 1–34, 2021, doi: 10.3390/toxics9030042.

X. Jiang, “Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis,” Chem Rev, vol. 120, no. 15, pp. 7984–8034, 2020, doi: 10.1021/acs.chemrev.9b00723.
Published
2024-03-21
How to Cite
Nassar, A. M. (2024). Investigating the Concentration of Heavy Elements in Soils from Thi-Qar Governorate. Central Asian Journal of Medical and Natural Science, 5(2), 44-50. https://doi.org/10.17605/cajmns.v5i2.2399
Section
Articles